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4 Biosynthesis and Degradation of Nucleotides 867 Ribose 5-phosphate ribose phosphate pyrophosphokinase ADP ADP ATP (PRPP synthetase) PRPP glutamine-PRPP amidotransferase AMP GMP IMP 5-Phosphoribosylamine 9 steps IMP adenylosuccinate synthetase AMP IMP dehydrogenase GMP Adenylosuccinate adenylosuccinate lyase AMP XMP-glutamine amidotransferase Fodex XMP Aspartate Carbamoyl aspartate trans- carbamoylase phosphate Pi OO C N-Carbamoylaspartate dihydroorotase H2O L-Dihydroorotate H2N CH2 C CH COO ON H O C HN CH2 C CH COO ON H O C dihydroorotate dehydrogenase NAD NADH H Orotate PRPP orotate phosphoribosyl- transferase PPi Orotidylate P OOCH2 O HN Ratws CC O N COO H O C HN CH CC O N COO HH HH orotidylate decarboxylase CO2 Uridylate (UMP) OHOH O C HN CH O O C CH Marrket P OOCH2 HH 2 ATP H H OH OH NH2 C N CH ADP Pi ON P P P OOCH2 O HH HH OH OH Cytidine 5-triphosphate (CTP) kinases 2ADP Uridine 5-triphosphate (UTP) Gln cytidylate Glu synthetase ATP C CH FIGURE forez Regulatory mechanisms in the biosynthesis of ade- nine and guanine nucleotides in E.

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